高效液相全波长扫描是怎么一回事

2025年04月06日 23:17
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全波长扫描是二极管阵列检测器特有的功能,二极管阵列检测器测定原理与紫外检测器一致,但是发光原理和数据采集原理不同。
液相色谱仪常用检测器为紫外检测器,他通过对特定波长下流通池内液体的吸收值来形成电信号,电信号在时间轴下连续显示形成峰,用以显示物质总量。二极管阵列检测器可以在同一时间(时间轴某一点)采集多个波长的信号(称为多通道),这些波长在该时间点下可以形成该时间点处吸收池内物质的紫外扫描图谱。这个紫外图谱就是所谓的全波长扫描。相对的紫外检测器就叫单波长扫描。还有一种紫外检测器通过牺牲图谱分辨率来达到双波长采集的方式,但与二极管阵列检测器的全波长扫描是有本质区别的。
说一个更具象的说法,在二极管阵列检测器下,如果说时间轴是X轴,信号是Y轴,那么波长就是Z轴,全波长扫描图谱就是在X轴固定下,Y轴与Z轴的关系。

附上二极管阵列检测器的原理:
二极管阵列检测器 即光电二级阵列管检测器又称光电二极管列阵检测器或光电二极管矩阵检测器,表示为PDA(photo-diode array)、PDAD(photo-diode array detector)或(Diode array detector,DAD)是20世纪80年代出现的一种光学多通道检测器。在晶体硅上紧密排列一系列光电二极管,每一个二极管相当于一个单色器的出口狭缝,二极管越多分辨率越高,一般是一个二极管对应接受光谱上一个纳米谱带宽的单色光。此外,还有的商家称之为多通道快速紫外-可见光检测器(multichannel rapid scanning UV-VIS detector),三维检测器(three dimensional detector)等。光电二极管阵列检测器目前已在高效液相色谱分析中大量使用,一般认为是液相色谱最有发展、最好的检测器。

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