【选做题--物质结构与性质】某氮铝化合物X具有耐高温、抗冲击、导热性好等优良性质,广泛用于陶瓷工业等

2025年04月07日 06:09
有1个网友回答
网友(1):

(1)氮是7号元素,核外电子数是5,核外电子排布式为1s22s22p3
故答案为:1s22s22p3
(2)根据X的晶体结构图可知,晶胞中含有氮原子为4,含有铝原子

1
8
×8+
1
2
×6
=4,所以X的化学式为AlN,氧化铝与氮气和碳在一定条件下反应的化学方程式为Al2O3+N2+3C=2AlN+3CO,
故答案为:AlN;Al2O3+N2+3C=2AlN+3CO;
(3)氮化硼与AlN相比,硼原子半径比铝原子半径小,所以键能就大,它们都是原子晶体,所以氮化硼的熔点比AlN高,
故答案为:氮化硼与氮化铝均为原子晶体,且硼原子半径小于铝原子半径,B-N键键能大于Al-N键键能;
(4)由AlN的晶胞结构可知,一个N原子与距离最近的四个Al原子成键,因此N采取sp3杂化,根据X的结构可知,每个铝和氮周围都有四个共价键,都达八电子稳定结构,而铝原子最外层原来只有三个电子,氮原子最外层有5个电子,所以在AlN中有配位键,根据AlN的性质可知它为原子晶体,所以晶体中含有共价键,
故答案为:sp3;BC;
(5)晶体N原子位于晶胞体对角线的
1
4
处,将体心与下底面相对的两顶点相连可构成等腰三角形,距离最近的两个N原子相连的连线为该三角形的中位线,所以晶体中最近的两个N原子的距离为底面对角线的
1
2

根据晶胞的密度ρ=
4×27+4×14
NA
晶胞边3
,可以求得晶胞边长为
3
164
ρ?NA
cm,
进而求得底面对角线的长度为
2
?
3
164
ρ?NA
cm,所以晶体中最近的两个N原子的距离为
2
2
?
3
164
ρ?NA
cm,
故答案为:

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